A DFT study on the mechanism of the sulfonic acid + alcohol esterification reaction
Author:
Affiliation:
1. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)
2. CSIC-Universidad de Zaragoza
3. E-50009 Zaragoza
4. Spain
Abstract
A DFT study reveals the unfeasibility of pentacoordinate sulfur intermediates in the sulfonic acid esterification reaction.
Funder
European Regional Development Fund
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C7RA09833B
Reference45 articles.
1. J.Hoyle , in Sulphonic Acids, Esters and their Derivatives , ed. S. Patai and Z. Rappoport , Wiley , Chichester, UK , 1991 , ch. 19, pp. 351–399
2. A New Method for the Esterification of Sulphonic Acids
3. Facile esterification of sulfonic acids and carboxylic acids with triethylorthoacetate
4. Reaction of carboxylic acid esters with p-toluenesulfonic acid.
5. A New Synthesis of Sulphonate Esters
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