Tuning the structure and photoinduced linkage isomerism of tetrapyridine nitrosyl ruthenium(ii) complexes by changing the trans-to-NO coordinated ligand
Author:
Affiliation:
1. Nikolaev Institute of Inorganic Chemistry
2. Siberian Branch of the Russian Academy of Science
3. Novosibirsk
4. Russia
5. Novosibirsk State University
Abstract
Ruthenium nitrosyl complexes were prepared with various trans-to-NO ligands. These compounds form Ru–ON metastable states upon blue-light excitation and the corresponding thermal stabilities were determined.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/NJ/C9NJ05862A
Reference37 articles.
1. Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes
2. Structural Influence on the Photochromic Response of a Series of Ruthenium Mononitrosyl Complexes
3. Photochemical nitrosyl linkage isomerism/metastable states
4. High thermal stability of the Ru–ON (MS1) linkage isomer of the ruthenium nitrosyl complex [RuNO(Py)4F](ClO4)2 with the trans NO–Ru–F coordinate
5. Long-lived light-induced metastable states in trans-[Ru(NH3)4(H2O)NO]Cl3·H2O and related compounds
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