Isolation of the elusive [Ru(bipy)<sub>3</sub>]<sup>+</sup>: a key intermediate in photoredox catalysis-Reference-Cited by-同舟云学术

Isolation of the elusive [Ru(bipy)₃]⁺: a key intermediate in photoredox catalysis

Published:2023 Issue:99 Volume:59 Page:14665-14668
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Horsewill Samuel J.¹^ORCID,Cao Chengyang²,Dabney Noah³,Yang Eric S.²^ORCID,Faulkner Stephen²^ORCID,Scott Daniel J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK

2. Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, OX1 3TA, UK

3. Department of Chemistry, Guilford College, 5800 W Friendly Ave., Greensboro, NC 27410, USA

Abstract

[Ru(bipy)3]+ is a key intermediate in the chemistry of the ubiquitous [Ru(bipy)3]2+, including in recent photoredox applications. Isolation helps to illuminate the monocation’s structure and potential roles in catalytic reactivity.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC04375D

Reference55 articles.

1. Light induced and dye accelerated reductions of phenacyl onium salts by 1,4-dihydropyridines

2. Chemistry of dihydropyridines. 9. Hydride transfer from 1,4-dihydropyridines to sp3-hybridized carbon in sulfonium salts and activated halides. Studies with NAD(P)H models

3. Tris(bipyridyl)ruthenium(II)-photosensitized reaction of 1-benzyl-1,4-dihydronicotinamide with benzyl bromide

4. Redox-photosensitized reactions. 11. Ru(bpy)32+-photosensitized reactions of 1-benzyl-1,4-dihydronicotinamide with aryl-substituted enones, derivatives of methyl cinnamate, and substituted cinnamonitriles: electron-transfer mechanism and structure-reactivity relationships

5. Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

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