Asymmetric organocatalytic desymmetrization of 4,4-disubstituted cyclohexadienones at high pressure: a new powerful strategy for the synthesis of highly congested chiral cyclohexenones-Reference-Cited by-同舟云学术

Asymmetric organocatalytic desymmetrization of 4,4-disubstituted cyclohexadienones at high pressure: a new powerful strategy for the synthesis of highly congested chiral cyclohexenones

Published:2014 Issue:31 Volume:12 Page:5847-5855
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Miyamae Naomu¹²³⁴,Watanabe Naruhisa¹²³⁴,Moritaka Maya¹²³⁴,Nakano Keiji¹²³⁴,Ichikawa Yoshiyasu¹²³⁴,Kotsuki Hiyoshizo¹²³⁴

Affiliation:

1. Laboratory of Natural Products Chemistry

2. Faculty of Science

3. Kochi University

4. Kochi 780-8520, Japan

Abstract

A highly diastereoselective and enantioselective method for the asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones at high pressure was developed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB00733F

Reference75 articles.

1. Asymmetric synthesis using homochiral lithium amide bases

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5. Asymmetric Alcoholysis of Cyclic Anhydrides

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