Rigidification of a macrocyclic tris-catecholate scaffold leads to electronic localisation of its mixed valent redox product-Reference-Cited by-同舟云学术

Rigidification of a macrocyclic tris-catecholate scaffold leads to electronic localisation of its mixed valent redox product

Published:2019 Issue:16 Volume:55 Page:2281-2284
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Greatorex Sam¹²³⁴,Vincent Kevin B.⁵⁶⁷⁴,Baldansuren Amgalanbaatar⁸⁹¹⁰⁴^ORCID,McInnes Eric J. L.⁸⁹¹⁰⁴,Patmore Nathan J.⁵⁶⁷⁴,Sproules Stephen¹¹¹²¹³⁴^ORCID,Halcrow Malcolm A.¹²³⁴^ORCID

Affiliation:

1. School of Chemistry

2. University of Leeds

3. Leeds LS2 9JT

4. UK

5. Department of Chemical Sciences

6. University of Huddersfield

7. Huddersfield HD1 3DH

8. School of Chemistry and Photon Science Institute

9. University of Manchester

10. Manchester M13 9PL

11. WestCHEM, School of Chemistry

12. University of Glasgow

13. Glasgow G12 8QQ

Abstract

One-electron oxidation of the compound shown shows no evidence for intervalence charge transfer in the macrocylic ligand radical product. In contrast, related [{Pt(L)}₃(μ₃-ctc˙)]⁺ (H₆ctc = cyclotricatechylene), exhibits class II mixed valency.

Funder

Engineering and Physical Sciences Research Council

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC10122A

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