On-surface synthesis and characterization of teranthene and hexanthene: ultrashort graphene nanoribbons with mixed armchair and zigzag edges

Author:

Borin Barin Gabriela1ORCID,Di Giovannantonio Marco1ORCID,Lohr Thorsten G.2,Mishra Shantanu1,Kinikar Amogh1ORCID,Perrin Mickael L.34,Overbeck Jan3,Calame Michel356ORCID,Feng Xinliang27ORCID,Fasel Roman18ORCID,Ruffieux Pascal1ORCID

Affiliation:

1. Nanotech@Surfaces Laboratory, Empa, Swiss Federal Laboratories for Materials Science and Technology, 8600 Dübendorf, Switzerland

2. Center for Advancing Electronics Dresden, Department of Chemistry and Food Chemistry, TU Dresden, Dresden 01062, Germany

3. Transport at Nanoscale Interfaces Laboratory, Empa, Swiss Federal Laboratories for Materials Science and Technology, 8600 Dübendorf, Switzerland

4. Department of Information Technology and Electrical Engineering, ETH Zurich, 8092 Zurich, Switzerland

5. Department of Physics, University of Basel, Klingelbergstrasse 82, CH-4056 Basel, Switzerland

6. Swiss Nanoscience Institute, University of Basel, Klingelbergstrasse 82, CH-4056 Basel, Switzerland

7. Max Planck Institute of Microstructure Physics, Weinberg 2, 06120 Halle, Germany

8. Department of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, 3012 Bern, Switzerland

Abstract

We present a detailed identification of molecular orbitals and vibrational modes of hexanthene and teranthene, assign their origin to armchair or zigzag edges, and discuss the chemical reactivity of these edges based on characteristic Raman spectral features.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Horizon 2020 Framework Programme

Office of Naval Research

Werner Siemens-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Reference68 articles.

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3. Atomically precise bottom-up fabrication of graphene nanoribbons

4. On-Surface Synthesis and Characterization of 9-Atom Wide Armchair Graphene Nanoribbons

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