Synthesis and reactivity of a terminal aluminium–imide bond-Reference-Cited by-同舟云学术

Synthesis and reactivity of a terminal aluminium–imide bond

Published:2020 Issue:15 Volume:56 Page:2288-2291
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Anker Mathew D.¹²³⁴^ORCID,Schwamm Ryan J.¹²³⁴^ORCID,Coles Martyn P.¹²³⁴^ORCID

Affiliation:

1. School of Chemical and Physical Sciences

2. Victoria University of Wellington

3. Wellington 6012

4. New Zealand

Abstract

The Al–N_imide bond in a new anionic aluminium imide complex reacts via a [2+2] cycloaddition with CO₂ to afford the dianionic carbamate ligand.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC09214E

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4. Synthesis and Structure of a Monomeric Aluminum(I) Compound [{HC(CMeNAr)2}Al] (Ar=2,6–iPr2C6H3): A Stable Aluminum Analogue of a Carbene

5. The unique β-diketiminate ligand in aluminum(i) and gallium(i) chemistry

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