High-efficiency electrosynthesis of urea over bacterial cellulose regulated Pd–Cu bimetallic catalyst-Reference-Cited by-同舟云学术

High-efficiency electrosynthesis of urea over bacterial cellulose regulated Pd–Cu bimetallic catalyst

Published:2023 Issue:1 Volume:1 Page:45-53
ISSN:2753-801X
Container-title:EES Catalysis
language:en
Short-container-title:EES. Catal.

Author:

Zhang Shengbo¹²,Geng Jing¹²,Zhao Zhong¹²,Jin Meng¹²,Li Wenyi¹²,Ye Yixing¹²,Li Ke³,Wang Guozhong¹²^ORCID,Zhang Yunxia¹²^ORCID,Yin Huajie¹²^ORCID,Zhang Haimin¹²^ORCID,Zhao Huijun⁴^ORCID

Affiliation:

1. Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China

2. University of Science and Technology of China, Hefei 230026, China

3. Key Laboratory of Agricultural Sensors, Ministry of Agriculture, School of Information and Computer, Anhui Agricultural University, Hefei 230026, China

4. Center for Catalysis and Clean Energy, Griffith University, Gold Coast Campus, QLD4222, Australia

Abstract

PdCu/CBC exhibited a remarkable Rurea of 763.8 ± 42.8 μg h−1 mgcat.−1 at −0.50 V (vs. RHE) and an exceptional FE of 69.1 ± 3.8% at −0.40 V (vs. RHE). Taking advantage of operando spectroscopy characterization, the C–N coupling mechanism was verified.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Anhui Province

Hefei Institutes of Physical Science, Chinese Academy of Sciences

China Postdoctoral Science Foundation

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2023/EY/D2EY00038E

Reference45 articles.

1. Electrochemical synthesis of urea on MBenes