A coordination driven self-assembled Pd6L8 nanoball catalyses copper and phosphine-free Sonogashira coupling reaction in both homogeneous and heterogeneous formats
Author:
Affiliation:
1. Department of Applied Chemistry
2. Indian School of Mines
3. Dhanbad-826004
4. India
Abstract
A self-assembled Pd6L8 nanocage catalysed copper free Sonogashira reaction under mild and aerobic conditions, at 100 ppm catalyst loading in aqueous medium in the homogeneous phase, and at 500 ppm in the heterogeneous phase.
Funder
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C5NJ03658E
Reference71 articles.
1. Palladium-Based Catalytic Systems for the Synthesis of Conjugated Enynes by Sonogashira Reactions and Related Alkynylations
2. A Guide to Sonogashira Cross-Coupling Reactions: The Influence of Substituents in Aryl Bromides, Acetylenes, and Phosphines
3. Sonogashira Coupling Reaction with Diminished Homocoupling
4. Synergistic Catalysis in the Sonogashira Coupling Reaction: Quantitative Kinetic Investigation of Transmetalation
5. Transition-Metal-Free Sonogashira-Type Cross-Coupling of Alkynes with Fluoroarenes
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