Reactivity of tetrel functionalized heptapnictogen clusters towards heteroallenes-Reference-Cited by-同舟云学术

Reactivity of tetrel functionalized heptapnictogen clusters towards heteroallenes

Published:2023 Issue:8 Volume:52 Page:2384-2391
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jobbins William D.¹^ORCID,van IJzendoorn Bono¹^ORCID,Vitorica-Yrezabal Inigo J.²,Whitehead George F. S.²^ORCID,Mehta Meera¹^ORCID

Affiliation:

1. Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

2. X-ray Diffraction Facility, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

Abstract

Isocyanates and carbon dioxide capture between the tetrel-pnictogen bonds of functionalized [P7] cages is investigated by NMR and IR spectroscopy, signal crystal X-ray diffraction, and density functional theory.

Funder

Royal Society

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT04074C

Reference46 articles.

1. Frontiers in the solution-phase chemistry of homoatomic group 15 Zintl clusters

2. A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes

3. Nucleophilic Activation of Red Phosphorus for Controlled Synthesis of Polyphosphides

4. Facile Conversion of Red Phosphorus into Soluble Polyphosphide Anions by Reaction with Potassium Ethoxide

5. Fibrous Red Phosphorus

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