Tracing mechanistic pathways and reaction kinetics toward equilibrium in reactive molten salts

Author:

Gibson Luke D.1ORCID,Roy Santanu2ORCID,Khanal Rabi1,Chahal Rajni2,Sedova Ada3,Bryantsev Vyacheslav S.2ORCID

Affiliation:

1. Computational Sciences and Engineering Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831, USA

2. Chemical Science Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831, USA

3. Bioscience Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831, USA

Abstract

In the dynamic environment of multi-component reactive molten salts, speciation unfolds as a complex process, involving multiple competing reaction pathways that are likely to face free energy barriers before reaching the reaction equilibria.

Funder

Office of Materials and Chemical Technologies

Office of Nuclear Energy

Oak Ridge National Laboratory

Office of Science

Publisher

Royal Society of Chemistry (RSC)

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