Cooperative B–H bond activation: dual site borane activation by redox active κ2-N,S-chelated complexes-Reference-Cited by-同舟云学术

Cooperative B–H bond activation: dual site borane activation by redox active κ²-N,S-chelated complexes

Published:2022 Issue:29 Volume:13 Page:8567-8575
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zafar Mohammad¹,Ahmad Asif¹,Saha Suvam¹,Ramalakshmi Rongala¹,Roisnel Thierry²^ORCID,Ghosh Sundargopal¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India

2. Univ of Rennes, CNRS, Institut des Sciences Chimiques de Rennes, UMR 6226, F-35042 Rennes, France

Abstract

Redox-active ruthenium complexes supported by hemilabile κ2-N,S-chelated ruthenacycles undergo unusual dual site B–H bond activation through metal–ligand cooperation with free and bulky boranes.

Funder

Indo-French Centre for the Promotion of Advanced Research

Indian Institute of Technology Madras

Council of Scientific and Industrial Research, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00907B

Reference69 articles.

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5. PN3(P)-Pincer Complexes: Cooperative Catalysis and Beyond

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