Amide bond cleavage initiated by coordination with transition metal ions and tuned by an auxiliary ligand-Reference-Cited by-同舟云学术

Amide bond cleavage initiated by coordination with transition metal ions and tuned by an auxiliary ligand

Published:2016 Issue:25 Volume:45 Page:10289-10296
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yang Yongpo¹²³,Lu Chunxin⁴⁵⁶⁷³,Wang Hailong⁴⁵⁶⁷³,Liu Xiaoming⁴⁵⁶⁷³

Affiliation:

1. School of Petrochemical Engineering Changzhou University

2. Changzhou

3. China

4. College of Biological

5. Chemical Sciences and Engineering

6. Jiaxing University

7. Jiaxing 314001

Abstract

To scission effectively an amide bond, it is essential for a metal centre to bind to the amide bond and the metal centre is of sufficient Lewis acidity which can be tuned by auxiliary ligands.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01411A

Reference29 articles.

1. Direct transition metal-catalyzed functionalization of heteroaromatic compounds

2. Metal ions in biological catalysis: from enzyme databases to general principles

3. Transition Metal Speciation in the Cell: Insights from the Chemistry of Metal Ion Receptors

4. Biological applications of X-ray fluorescence microscopy: exploring the subcellular topography and speciation of transition metals

5. Boon and Bane of Metal Ions in Medicine

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