Single-crystal X-ray diffraction study, NMR and electrochemical analysis of a copper(i) 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis-[(6-methyl-2,2′-bipyridyl-6-yl)methoxy]calix[4]arene complex: an original M4L2 “hand-to-hand” system

Author:

Regnouf-de-Vains J.-B.12345ORCID,Malaman B.12675,Bouguet-Bonnet S.12845,Poinsignon Sophie12845ORCID,Leclerc Sébastien12945ORCID,Beley M.12345

Affiliation:

1. Université de Lorraine

2. CNRS

3. L2CM

4. F-54000 Nancy

5. France

6. Institut Jean Lamour (IJL)

7. F-54506 Nancy

8. CRM2

9. LEMTA

Abstract

An original M4L2 “hand-to-hand” copper(i)/tetra-bipyridyl-calix[4]arene complex was obtained and characterized in the solid state by X-ray diffraction. It changes in MeCN solution to its M2L analogue.

Funder

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference40 articles.

1. C. D. Gutsche , in Syntheses of macrocycles, the design of selective complexing agents, Progress inMacrocyclic Chemistry , ed. R. M. Izatt and J. J. Christensen , John Wiley and Sons , New York , 1987 , vol. 3, pp. 93–166

2. C. D. Gutsche , in “Calixarenes”, Monographs in Supramolecular Chemistry , ed. J. F. Stoddart , Royal Society of Chemistry , Cambridge , 1989

3. Calixarenes. A Versatile Class of Macrocyclic Compounds , ed. J. Vicens and V. Böhmer , Kluwer Academic Publishers , Dordrecht , 1991

4. Calixarenes in the nanoworld , ed. J. Vicens , J. Harrowfield and L. Baklouti , Kluwer , Dordrecht, The Netherlands , 2007

5. C. D. Gutsche , Calixarenes Revisited , Royal Society of Chemistry , Cambridge , 1998

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