Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions

Author:

Jiang Zhuoli12345,Sun Wenming6785,Shang Huishan12345,Chen Wenxing12345,Sun Tingting91011125,Li Haijing131415165,Dong Juncai131415165,Zhou Jing171819205,Li Zhi1021225,Wang Yu171819205,Cao Rui23242526,Sarangi Ritimukta23242526,Yang Zhengkun102728295,Wang Dingsheng1021225ORCID,Zhang Jiatao12345ORCID,Li Yadong1021225ORCID

Affiliation:

1. Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

2. School of Materials Science and Engineering

3. Beijing Institute of Technology

4. Beijing 100081

5. China

6. College of Science

7. China Agricultural University

8. Beijing 100193

9. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials

10. Department of Chemistry

11. University of Science and Technology Beijing

12. Beijing 100083

13. Beijing Synchrotron Radiation Facility

14. Institute of High Energy Physics

15. Chinese Academy of Sciences

16. Beijing 100049

17. Shanghai Synchrotron Radiation Facility

18. Shanghai Institute of Applied Physics

19. Chinese Academy of Science

20. Shanghai 201800

21. Tsinghua University

22. Beijing 100084

23. Stanford Synchrotron Radiation Lightsource

24. SLAC National Accelerator Laboratory

25. Menlo Park

26. USA

27. Collaborative Innovation Center of Chemistry for Energy Materials

28. University of Science and Technology of China

29. Hefei 230026

Abstract

By the in situ X-ray absorption results, the gradually decrease of Cu oxidation state under applied potential implied that low-valence Cu (+1) species in the atomic interface of Cu–N4–C8S2 may work as the catalytic sites during an ORR process.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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