Diffusion of single molecular and macromolecular probes during the free radical bulk polymerization of MMA – towards a better understanding of the Trommsdorff effect on a molecular level-Reference-Cited by-同舟云学术

Diffusion of single molecular and macromolecular probes during the free radical bulk polymerization of MMA – towards a better understanding of the Trommsdorff effect on a molecular level

Published:2016 Issue:24 Volume:7 Page:4100-4105
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Nölle Jan Martin¹²³⁴,Primpke Sebastian⁵⁶⁷⁴,Müllen Klaus⁵⁸⁹⁴,Vana Philipp⁵⁶⁷⁴,Wöll Dominik¹²³⁴¹⁰

Affiliation:

1. Fachbereich Chemie

2. Universität Konstanz

3. D-78457 Konstanz

4. Germany

5. Institute of Physical Chemistry

6. Universität Göttingen

7. D-37077 Göttingen

8. Johannes Gutenberg University Mainz

9. D-55128 Mainz

10. Zukunftskolleg

Abstract

Diffusional heterogeneities of molecular and macromolecular probes were studied during the radical bulk polymerization of methyl methacrylate using fluorescence microscopy methods.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C6PY00590J

Reference37 articles.

1. Chain-length-dependent termination in radical polymerization: Subtle revolution in tackling a long-standing challenge

2. Zur polymerisation des methacrylsäuremethylesters1

3. CATALYSED POLYMERIZATION OF METHYL METHACRYLATE IN THE LIQUID PHASE

4. The rate of copolymerization of styrene and methyl methacrylate—II. The gel effect in copolymerization

5. Rheokinetics and the influence of shear rate on the Trommsdorff (gel) effect during free radical polymerization

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