Cyclopentadienylcobalt azaboranes violating the Wade–Mingos rules: a degree 3 vertex for the nitrogen atom-Reference-Cited by-同舟云学术

Cyclopentadienylcobalt azaboranes violating the Wade–Mingos rules: a degree 3 vertex for the nitrogen atom

Published:2015 Issue:70 Volume:5 Page:56885-56890
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Attia Amr A. A.¹²³⁴⁵,Lupan Alexandru¹²³⁴⁵,King R. Bruce⁶⁷⁸⁹

Affiliation:

1. Department of Chemistry

2. Faculty of Chemistry and Chemical Engineering

3. Babeş-Bolyai University

4. Cluj-Napoca

5. Romania

6. Department of Chemistry and Center for Computational Quantum Chemistry

7. University of Georgia

8. Athens

9. USA

Abstract

The structures and energetics of the cobaltaazaboranes CpCoNHB_n−2H_n−2 (n = 8 to 12) have been investigated by density functional theory. Degree 3 vertices are found for the nitrogen atoms in low-energy 8- and 9-vertex structures.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA09849A

Reference16 articles.

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2. Synthesis and X-ray structure of 4-azanonaborane(13)(4-NB8H13)

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4. The structural significance of the number of skeletal bonding electron-pairs in carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds

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