Synthesis and properties of a novel Cu(ii)–pyridineoxazoline containing polymeric catalyst for asymmetric Diels

Synthesis and properties of a novel Cu(ii)–pyridineoxazoline containing polymeric catalyst for asymmetric Diels–Alder reaction

Published:2015 Issue:4 Volume:5 Page:2882-2890
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wang Heng¹²³⁴⁵,Li Na¹²³⁴⁵,Yan Zijia¹²³⁴⁵,Zhang Jie¹²³⁴⁵,Wan Xinhua¹²³⁴⁵

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. Key Laboratory of Polymer Chemistry and Physics of Ministry of Education

3. College of Chemistry and Molecular Engineering

4. Peking University

5. Beijing 100871

Abstract

Soluble and recyclable Cu(ii)–pyridineoxazoline containing polymeric catalyst shows faster reaction rate and higher enantio-selectivity than its low molecular mass counterpart in D–A reaction of 2-alkenoyl pyridine N-oxide and cyclopentadiene.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA13883J

Reference52 articles.

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5. D. E. De Vos , I. F. J.Vankelecom and P. A.Jacobs, Chiral Catalyst Immobilization and Recycling, Wiley-VCH Verlag GmbH, 2000

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