Competitive coordination and Lewis-base interactions of amines in supertetrahedral cluster-based materials by a controllable naked T3-InS precursor method: from isolated clusters with various substituted ligands, chains to 3-D open frameworks

Abstract

The regulation of amines can convert ligand-free T3-InS clusters into a variety of products. These results indicate that the coordination ability N atoms of amines has an important influence on the formation and assembly mode of clusters.