Update and critical reanalysis of IUPAC benchmark propagation rate coefficient data

Author:

Beuermann Sabine1ORCID,Harrisson Simon2ORCID,Hutchinson Robin A.3ORCID,Junkers Tanja4ORCID,Russell Gregory T.5ORCID

Affiliation:

1. Institute of Technical Chemistry, Clausthal University of Technology, Arnold-Sommerfeld-Straße 4, 38678 Clausthal-Zellerfeld, Germany

2. Laboratoire de Chimie des Polymères Organiques, Université de Bordeaux/ENSCBP/CNRS, UMR 5629, F-33600 Pessac, France

3. Department of Chemical Engineering, Queen's University, 19 Division St. Kingston ON K7L 3N6, Canada

4. School of Chemistry, Monash University, 19 Rainforest Walk, Clayton, VIC 3800, Australia

5. School of Physical and Chemical Sciences, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand

Abstract

The dataset used to generate IUPAC benchmark Arrhenius parameters for propagation rate coefficients in radical polymerization is extended and reanalyzed, taking into account systematic interlaboratory variation.

Funder

International Union of Pure and Applied Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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