Protonation of Verkade bases: a theoretical study-Reference-Cited by-同舟云学术

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Protonation of Verkade bases: a theoretical study

Published:2019 Issue:6 Volume:43 Page:2575-2582
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ullah Sabnam S.¹²³⁴⁵,Rohman Shahnaz S.¹²³⁴⁵,Kashyap Chayanika¹²³⁴⁵,Guha Ankur Kanti¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Cotton University

3. Panbazar

4. Guwahati

5. India 781001

Abstract

The dilemma of favorable protonation at less basic phosphorus rather than more basic nitrogen in Verkade bases has been resolved.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C8NJ04977G

Reference54 articles.

1. pKa Measurements of P(RNCH2CH3)3N

2. The "anomalous" basicity of P(NHCH2CH2)3N relative to P(NMeCH2CH2)3N and p(NBzCH2CH2)3N: a chemical consequence of orbital charge balance?

3. The unusually robust phosphorus-hydrogen bond in the novel cation [cyclic] HP(NMeCH2CH2)3N+

4. Unusually Lewis basic Pro-azaphosphatranes

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