Rational design, crystal structures and sensing properties of a series of luminescent MOFs based on a flexible tetracarboxylate ligand and N-donor ligands

Author:

Chen Xiao-Li12345ORCID,Cui Hua-Li12345,Yang Hua12345,Wang Xiao12345,Liu Ling12345,Ren Yi-Xia12345ORCID,Wang Ji-Jiang12345ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Shaanxi Key Laboratory of Chemical Reaction Engineering

3. Laboratory of New Energy and New Function Materials

4. Yanan University

5. Yan'an 716000

Abstract

Six Zn/Cd MOFs were synthesized and characterized. 1–3 are 1D ring chains. 4–5 show 2D bilayer network. 6 possesses a 3D network structure. In particular, 2 demonstrates highly selective and sensitive luminescent sensor towards acetone and Fe3+ ion.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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