Photo-induced tungsten-catalyzed cascade synthesis of pyrrolo[2,1-<i>a</i>]isoquinoline-1,3-dicarboxylate and its reaction mechanism-Reference-Cited by-同舟云学术

Photo-induced tungsten-catalyzed cascade synthesis of pyrrolo[2,1-a]isoquinoline-1,3-dicarboxylate and its reaction mechanism

Published:2024 Issue:34 Volume:60 Page:4573-4576
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wen Yongshun¹,Jin Hong-Xian¹,Qiu Yan-Hua¹,Zong Yingtong¹,Luo Wenjun¹,Chen Zhengwang¹^ORCID,Yu Daohong¹^ORCID

Affiliation:

1. Key laboratory of Organo-Pharmaceutical Chemistry of Jiangxi Province, Gannan Normal University, 341000, China

Abstract

Tungsten-catalysed [3+2]-cycloaddition aromatization was developed. Mechanistic experiments revealed that the formation of an ion-pair intermediate is crucial for the cascade process. The cycloadduct acid was confirmed by X-ray diffraction.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangxi Province

Education Department of Jiangxi Province

Gannan Normal University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00169A

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