Unraveling the amine oxidative coupling activity of hierarchical porous Fe–N<sub>4</sub>–O<sub>1</sub> single-atom catalysts: oxygen atom-mediated dual reaction pathway-Reference-Cited by-同舟云学术

Unraveling the amine oxidative coupling activity of hierarchical porous Fe–N₄–O₁ single-atom catalysts: oxygen atom-mediated dual reaction pathway

Published:2022 Issue:46 Volume:10 Page:24831-24838
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

He Hongwei¹²³,Ma Kui⁴^ORCID,Liu Huibin¹²³,Li Jing¹²³,Zheng Lirong⁵^ORCID,Zhang Fengbao¹²³,Fan Xiaobin¹²³^ORCID,Peng Wenchao¹²³^ORCID,Ji Junyi⁴^ORCID,Li Yang¹²³^ORCID

Affiliation:

1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300354, P. R. China

2. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. China

3. Institute of Shaoxing, Tianjin University, Zhejiang 312300, P. R. China

4. School of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China

5. Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

Fe–NC with Fe–N4–O1 active sites exhibits splendid catalytic activity toward the selective oxidation of amines. A possible mechanism combining the oxidative pathway and ROS pathway in the presence of Fe–NC is proposed.

Funder

National Natural Science Foundation of China

Department of Science and Technology of Sichuan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TA/D2TA07198C

Reference46 articles.

1. Aerobic oxidative coupling of amines to imines by mesoporous copper aluminum mixed metal oxides via generation of Reactive Oxygen Species (ROS)

2. Influence of the halide and exposed facets on the visible-light photoactivity of bismuth oxyhalides for selective aerobic oxidation of primary amines