3D <i>vs.</i> turbostratic: controlling metal–organic framework dimensionality <i>via N</i>-heterocyclic carbene chemistry-Reference-Cited by-同舟云学术

3D vs. turbostratic: controlling metal–organic framework dimensionality via N-heterocyclic carbene chemistry

Published:2022 Issue:21 Volume:13 Page:6418-6428
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kochetygov Ilia¹^ORCID,Justin Anita¹^ORCID,Asgari Mehrdad¹²^ORCID,Yang Shuliang¹³,Karve Vikram¹,Schertenleib Till¹^ORCID,Stoian Dragos⁴,Oveisi Emad⁵^ORCID,Mensi Mounir¹,Queen Wendy L.¹^ORCID

Affiliation:

1. Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), CH-1951 Sion, Switzerland

2. Department of Chemical Engineering & Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, UK

3. College of Energy, Xiamen University, Xiamen, Fujian, 361102, China

4. Swiss–Norwegian Beamlines, ESRF, BP 220, Grenoble, 38043, France

5. Interdisciplinary Centre for Electron Microscopy (CIME), École Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland

Abstract

A new MOF with a saturated N-heterocyclic carbene ligand undergoes a series of structural transformations to produce a turbostratic material, which serves as a better support for an iridium hydrogenation catalyst, when compared to the parent material.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01041K

Reference53 articles.

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4. An experimental and computational study of CO2adsorption in the sodalite-type M-BTT (M = Cr, Mn, Fe, Cu) metal–organic frameworks featuring open metal sites

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