Synthesis of phosphine oxide based amphiphilic molecules via ring-opening Wittig olefination of a macrocyclic phosphoranylidene and their property study as non-ionic surfactants
Author:
Affiliation:
1. Organic Chemistry
2. Institute of Chemical and Engineering Sciences (ICES)
3. A*STAR
4. Singapore
5. Polymer Engineering & Characterisation
6. Jurong Island
Abstract
A novel ring-opening Wittig olefination approach was developed for the synthesis of amphiphilic phosphine oxides (PO) as non-ionic surfactants.
Funder
Agency for Science, Technology and Research
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA03324B
Reference22 articles.
1. The Wittig olefination reaction and modifications involving phosphoryl-stabilized carbanions. Stereochemistry, mechanism, and selected synthetic aspects
2. Recycling the Waste: The Development of a Catalytic Wittig Reaction
3. Wittig Reactions in Water Media Employing Stabilized Ylides with Aldehydes. Synthesis of α,β-Unsaturated Esters from Mixing Aldehydes, α-Bromoesters, and Ph3P in Aqueous NaHCO3
4. Enabling Wittig reaction on site-specific protein modification
5. Stabilized Wittig olefination for bioconjugation
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1. Synthesis of Aryldiphenylphosphine Oxides by Quaternization of Tertiary Diphenylphosphines with Aryl Bromides Followed by the Wittig Reaction;ACS Omega;2020-06-23
2. Influence factors on the critical micelle concentration determination using pyrene as a probe and a simple method of preparing samples;Royal Society Open Science;2020-03
3. Phosphine chalcogenides;Organophosphorus Chemistry;2020
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