Carbene functionalization of porphyrinoids through tosylhydrazones-Reference-Cited by-同舟云学术

Carbene functionalization of porphyrinoids through tosylhydrazones

Published:2021 Issue:42 Volume:19 Page:9199-9210
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kozhemyakin Grigory L.¹,Tyurin Vladimir S.¹^ORCID,Shkirdova Alena O.¹,Belyaev Evgeny S.¹^ORCID,Kirinova Ekaterina S.¹,Ponomarev Gelii V.²,Chistov Alexey A.³,Aralov Andrey V.³^ORCID,Tafeenko Victor A.⁴,Zamilatskov Ilya A.¹^ORCID

Affiliation:

1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Leninskiy prospect, 31-4, Moscow, 119071, Russian Federation

2. Research Institute of Biomedical Chemistry, Pogodinskaya str., 10-8, 119121, Moscow, Russian Federation

3. Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry, Miklukho-Maklaya str., 16/10, 117997, Moscow, Russian Federation

4. Chemistry Department, Moscow State University, Leninskiye Gory, 1-3, 119899 Moscow, Russian Federation

Abstract

Porphyrinoid functionalization was performed through carbenes obtained in situ from tosylhydrazones. Annulated tetrapyrrole macrocycles were formed via intramolecular C–H insertion of carbenes.

Funder

Russian Foundation for Basic Research

Russian Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01626A

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