Ultra-stiff and tough hydrogels based on small but strong hydrophobic associations via a low-reactive hydrophilic monomer

Author:

Yang Lei123,Li Shuo123,Zhao Zijian123,Wang Jie34,Lv Hongying13,Yang Xiaoniu123ORCID

Affiliation:

1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, P. R. China

2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Jinzhai Road No 96, Hefei 230026, P. R. China

3. CAS Key Laboratory of High-Performance Synthetic Rubber and its Composite Materials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, P. R. China

4. Huangpu Institute of Materials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Lianyun Road No 388, Guangzhou 510530, China

Abstract

Strong hydrophobic associations were formed between hydrophobic moiety-protected carbamate side groups of monomers, whose density and strength were regulated by using a low-reactive hydrophilic monomer to prepare ultra-stiff and tough hydrogels.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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