Addressing the role of triphenylphosphine in copper catalyzed ATRP
Author:
Affiliation:
1. Centre for Mechanical Engineering Materials and Processes (CEMMPRE)
2. Department of Chemical Engineering
3. University of Coimbra
4. 3030-790 Coimbra
5. Portugal
6. Department of Chemical Sciences
7. University of Padova
8. 35131 Padova
9. Italy
Abstract
A new Atom Transfer Radical Polymerization (ATRP) process with triphenylphosphine (PPh3) and [CuIIMe6TREN]2+ as the catalyst system is reported.
Funder
Fundação para a Ciência e a Tecnologia
Fondazione Cassa di Risparmio di Padova e Rovigo
Università degli Studi di Padova
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2018/PY/C8PY01245H
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1. Controlled/living radical polymerization: Features, developments, and perspectives
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3. Macromolecular Engineering by Atom Transfer Radical Polymerization
4. Kinetics of Fe-Mediated ATRP with Triarylphosphines
5. Enhanced Activity of ATRP Fe Catalysts with Phosphines Containing Electron Donating Groups
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