Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes-Reference-Cited by-同舟云学术

Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes

Published:2015 Issue:33 Volume:44 Page:14842-14853
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Böttcher Tobias¹²³⁴,Jones Cameron¹²³⁴

Affiliation:

1. School of Chemistry

2. Monash University

3. Melbourne

4. Australia

Abstract

The synthesis of a series of extremely bulky secondary amines with a phosphine function, Ar^†(PR₂)NH (Ar^†= C₆H₂{C(H)Ph₂}₂Prⁱ-2,6,4; R = Ph, NEt₂, NPrⁱ₂) is described. Deprotonation with eithern-BuLi or KH yields the respective alkali metal amides. Reactions with a series of chlorosilanes allows access to monomeric molecular compounds bearing the extremely bulky amino substituentsviasalt elimination.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02504D

Reference62 articles.

1. Dalton Discussion 11: The renaissance of main group chemistry

2. Modern Main Group Chemistry: From Renaissance to Revolution

3. Addition of H2 to distannynes under ambient conditions

4. Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

5. Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

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