ArNMeCH(SiMe3)2: a useful precursor of formal α-aminoalkyl diradicals in visible-light-mediated homo- and hetero-diaddition with alkenes-Reference-Cited by-同舟云学术

ArNMeCH(SiMe3)2: a useful precursor of formal α-aminoalkyl diradicals in visible-light-mediated homo- and hetero-diaddition with alkenes

Published:2020 Issue:54 Volume:56 Page:7487-7490
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liu Shunfa¹²³⁴⁵,Yang Yufan¹²³⁴⁵,Gao Lu¹²³⁴⁵,Song Zhenlei¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province

2. Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology

3. West China School of Pharmacy

4. Sichuan University

5. Chengdu

Abstract

ArNMeCH(SiMe₃)₂has been developed as a useful precursor of a formal α-aminoalkyl diradical in visible-light-mediated homo-diaddition with two identical alkenes in one-pot, or hetero-diaddition with two different alkenesviaa sequential operation.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC02277B

Reference48 articles.

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2. Radical translocation reactions in synthesis

3. Direct α-Functionalization of Saturated Cyclic Amines

4. Direct sp3C–H bond activation adjacent to nitrogen in heterocycles

5. Recent developments in cyclization reactions of α-aminoalkyl radicals

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