Complexation of An(vi) with succinic acid in aqueous acid solutions: uranyl vs. plutonyl

Author:

Sladkov V.12345ORCID,Bessonov A. A.678,Roques J.12345,Charushnikova I. A.678,Fedosseev A. M.678

Affiliation:

1. Institut de Physique Nucléaire

2. IN2P3-CNRS

3. Université Paris-Sud

4. Université Paris-Saclay

5. F-91406 Orsay Cedex

6. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences (IPCE RAS)

7. 199071 Moscow

8. Russia

Abstract

Due to stronger electrostatic interaction in a uranyl–succinate system, complex species of U(vi) with succinate are more stable than the ones of Pu(vi).

Funder

Centre National de la Recherche Scientifique

Université Paris-Sud

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference49 articles.

1. Radionuclide Behaviour in the Natural Environment , ed. C. Poinssot and H. Geckeis , Woodhead Publishing Ltd , Oxford , 2012

2. Mobile fission and activation products in nuclear waste disposal

3. W. Hummel , G.Anderegg , I.Puigdomènech and L.Rao , Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Ts, Se, Ni and Zr with Selected Organic Ligands , Elsevier Science Publishers B.V ., North-Holland, Amsterdam , 2005

4. Aqueous Uranium(VI) Complexes with Acetic and Succinic Acid: Speciation and Structure Revisited

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