Synthesis of tetrahalide dianions directed by crystal engineering
Author:
Affiliation:
1. Institute of Inorganic Chemistry
2. RWTH Aachen University
3. Aachen, Germany
4. Department of Chemistry
5. Nanoscience Centre
6. University of Jyvaskyla
7. 40014 Jyvaskyla, Finland
Abstract
The analogy between hydrogen bonds and halogen bonds was used to synthesize the unstable [X⋯I–I⋯X]2− species by trapping I2 in the channels of macrocyclic compounds.
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CE/C5CE01288K
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