Molecular 1,1′-bifunctional mixed-valence P–P compounds, enabled through metal complexation
Author:
Affiliation:
1. Institute of Inorganic Chemistry
2. Rheinische Friedrich-Wilhelms-Universität Bonn
3. 53121 Bonn
4. Germany
5. Department of Chemistry
6. University of the Balearic Islands
7. 07122 Palma (Baleares)
8. Spain
Abstract
Synthesis of a new class of 1,1′-bifunctional phosphanylidene phosphorane complexes (A, C) is described and the chemistry of dinuclear diphosphene complex B investigated in terms of 1,1- vs. 1,2-addition reactions.
Funder
Deutsche Forschungsgemeinschaft
Agencia Estatal de Investigación
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04070C
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