CpFe(CO)2 anion-catalyzed highly efficient hydrosilylation of ketones and aldehydes-Reference-Cited by-同舟云学术

CpFe(CO)2 anion-catalyzed highly efficient hydrosilylation of ketones and aldehydes

Published:2021 Issue:32 Volume:50 Page:11016-11020
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lou Ke¹^ORCID,Zhou Qingyang²,Wang Qi²,Fan Xingchao¹,Xu Xiufang²^ORCID,Cui Chunming¹^ORCID

Affiliation:

1. State Key Laboratory of Elemento-organic Chemistry and College of Chemistry, Nankai University, Tianjin 300071, China

2. Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071 China

Abstract

K[CpFe(CO)2] and [NEt4][CpFe(CO)2] enabled highly efficient hydrosilylation of ketones and aldehydes with PhSiH3 to synthesize tris- and bis(alkoxy)silanes in excellent yields depending on the substituents on the carbonyl compounds.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01778K

Reference42 articles.

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2. Recent advances in catalytic hydrosilylation of carbonyl groups mediated by well-defined first-row late transition metals

3. N-Acetyl-N,N-dipyrid-2-yl (cyclooctadiene) rhodium (I) and iridium (I) complexes: Synthesis, X-ray structures, their use in hydroformylation and carbonyl hydrosilylation reactions and in the polymerization of diazocompounds