Mechanistic understanding of ethane dehydrogenation and aromatization over Zn/ZSM-5: effects of Zn modification and CO2 co-reactant-Reference-Cited by-同舟云学术

Mechanistic understanding of ethane dehydrogenation and aromatization over Zn/ZSM-5: effects of Zn modification and CO2 co-reactant

Published:2020 Issue:24 Volume:10 Page:8359-8373
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Fan Huahua¹²³⁴⁵,Nie Xiaowa¹²³⁴⁵^ORCID,Wang Haozhi¹²³⁴⁵,Janik Michael J.⁶⁷⁸⁹,Song Chunshan¹²³⁴⁵,Guo Xinwen¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. PSU-DUT Joint Center for Energy Research

3. School of Chemical Engineering

4. Dalian University of Technology

5. Dalian 116024

6. EMS Energy Institute

7. PSU-DUT Joint Center for Energy Research, and Department of Chemical Engineering

8. The Pennsylvania State University

9. USA

Abstract

DFT calculations identified the promotional role of introducing a Zn modifier to HZSM-5 in ethane dehydrogenation/aromatization. The CO₂-assisted effect would be achieved by using bimetallic-modified catalysts such as Zn–Pt/ZSM5 and Zn–Fe/ZSM-5.

Funder

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY01566K

Reference60 articles.

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3. Light hydrocarbons to BTEX aromatics over Zn-modified hierarchical ZSM-5 combined with enhanced catalytic activity and stability