Possible atmospheric source of NH2SO3H: the hydrolysis of HNSO2 in the presence of neutral, basic, and acidic catalysts

Author:

Zhang Tianlei1ORCID,Zhang Yongqi1,Tian Shiyu1,Zhou Mi1,Liu Dong1,Lin Ling1,Zhang Qiang1,Wang Rui1ORCID,Muthiah Balaganesh2ORCID

Affiliation:

1. Institute of Theoretical and Computational Chemistry, Shaanxi Key Laboratory of Catalysis, School of Chemical & Environment Science, Shaanxi University of Technology, Hanzhong, Shaanxi 723001, P. R. China

2. Department of Chemistry, National Taiwan University, Taipei 106, Taiwan

Abstract

The hydrolysis reaction of HNSO2 without and with neutral, basic and acidic catalysts have been studied theoretically. The results were shown that neutral, basic and acidic catalysts could promote the formation of NH2SO3H both kinetically and thermodynamically.

Funder

Education Department of Shaanxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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