Reversible CO2 binding triggered by metal–ligand cooperation in a rhenium(i) PNP pincer-type complex and the reaction with dihydrogen-Reference-Cited by-同舟云学术

Reversible CO2 binding triggered by metal–ligand cooperation in a rhenium(i) PNP pincer-type complex and the reaction with dihydrogen

Published:2014 Issue:5 Volume:5 Page:2043-2051
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Vogt Matthias¹²³,Nerush Alexander¹²³,Diskin-Posner Yael¹⁴³,Ben-David Yehoshoa¹²³,Milstein David¹²³

Affiliation:

1. The Weizmann Institute of Science

2. Department of Organic Chemistry

3. Rehovot, Israel

4. Department of Chemical Research Support

Abstract

Metal–ligand cooperation in a rhenium PNP pincer complex gives rise to the reversible activation of CO₂ and H₂ and the efficient catalytic decomposition of formic acid under base-free conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC00130C

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5. Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

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