Diastereoisomeric enrichment of 1,4-enediols and H<sub>2</sub>-splitting inhibition on Pd-supported catalysts-Reference-Cited by-同舟云学术

Diastereoisomeric enrichment of 1,4-enediols and H₂-splitting inhibition on Pd-supported catalysts

Published:2023 Issue:35 Volume:21 Page:7136-7140
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ballesteros-Soberanas Jordi¹,Mon Marta¹,Leyva-Pérez Antonio¹^ORCID

Affiliation:

1. Instituto de Tecnología Química (UPV-CSIC), Universidad Politècnica de València-Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos s/n, 46022 Valencia, Spain

Abstract

The semi-hydrogenation reaction of gemini alkynes proceeds with palladium-supported catalysts in a diastereoisomerically-enriched way to give mainly meso 1,4-enediols, which inhibit the dissociation of H2 on the palladium catalyst.

Funder

Ministerio de Ciencia e Innovación

‘la Caixa’ Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB01025B

Reference37 articles.

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2. Molecular understanding of alkyne hydrogenation for the design of selective catalysts

3. Monophasic Catalytic System for the Selective Semireduction of Alkynes

4. Two-directional chain synthesis and terminus differentiation

5. Stereoisomeric Composition of Natural Myrtucommulone A

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