One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds-Reference-Cited by-同舟云学术

One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds

Published:2021 Issue:35 Volume:12 Page:11864-11872
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jia Xiangqing¹^ORCID,Nitsch Jörn¹,Wu Zhu¹,Friedrich Alexandra¹^ORCID,Krebs Johannes¹,Krummenacher Ivo¹,Fantuzzi Felipe¹²^ORCID,Braunschweig Holger¹^ORCID,Moos Michael³,Lambert Christoph³^ORCID,Engels Bernd²^ORCID,Marder Todd B.¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

2. Institut für Physikalische und Theoretische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

3. Institut für Organische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

Abstract

Stepwise chemical reduction of D–π–A triarylborane-based helicenes gives the corresponding monoanions and dianions with delocalized unpaired electrons. The structures were confirmed by single crystal X-ray diffraction.

Funder

China Scholarship Council

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02409D