5,20-Bis(α-oligothienyl)-substituted [26]hexaphyrins possessing electronic circuits strongly perturbed by meso-oligothienyl substituents-Reference-Cited by-同舟云学术

5,20-Bis(α-oligothienyl)-substituted [26]hexaphyrins possessing electronic circuits strongly perturbed by meso-oligothienyl substituents

Published:2015 Issue:3 Volume:6 Page:1696-1700
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mori Hirotaka¹²³⁴⁵,Suzuki Masaaki¹²³⁴⁵,Kim Woojae⁶⁷⁸,Lim Jong Min⁶⁷⁸,Kim Dongho⁶⁷⁸,Osuka Atsuhiro¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Kyoto University Sakyo-ku

4. Kyoto 606-8502

5. Japan

6. Spectroscopy Laboratory for Functional π-Electronic Systems and Department of Chemistry Yonsei University

7. Seoul 120-749

8. Korea

Abstract

A series of [26]hexaphyrins(1.1.1.1.1.1) bearing two α-oligothienyl substituents at 5,20-positions have been synthesised and are shown to have a dumbbell hexaphyrin conformation, to which the α-oligothienyl groups are linked to form an acyclic helix-like conjugated network.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03394A

Reference31 articles.

1. Expanded Porphyrins and Their Heterologs

2. Confusion, inversion, and creation—a new spring from porphyrin chemistry

3. Synthetic Expanded Porphyrin Chemistry