CO2 activation by permethylpentalene amido zirconium complexes
Author:
Affiliation:
1. Chemistry Research Laboratory
2. Department of Chemistry
3. University of Oxford
4. Oxford
5. UK
Abstract
Synthesis and characterisation of new permethylpentalene (Pn*) zirconium bis(amido) and Pn*Zr cyclopentadienyl mono(amido) complexes and their reactivity with carbon dioxide.
Funder
SCG Chemicals
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00770J
Reference37 articles.
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3. Standard heats of formation and M–C bond energy terms for some homoleptic transition metal alkyls MRn
4. The hexamethylpentalene dianion and other reagents for organometallic pentalene chemistry
5. Bonding in pentalene complexes and their recent applications
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1. Small, Electron-Donating Substituents Give CO2 Activation by Permethylpentalene Zirconium Amido Complexes the Upper Hand: A DFT Study of Distortion and Interaction;Inorganic Chemistry;2023-02-08
2. Titanium(IV) Alkoxide‐Carbamate Complexes: Synthesis and Catalytic Potential in H 2 O 2 ‐Oxidation of Organic Sulfides;European Journal of Inorganic Chemistry;2022-08-23
3. Non-redox reactivity of V(ii) and Fe(ii) formamidinates towards CO2 resulting in the formation of novel M(ii) carbamates;Dalton Transactions;2022
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