Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex toward polar multiple bonds
Author:
Affiliation:
1. Department of Molecular and Macromolecular Chemistry
2. Graduate School of Engineering
3. Nagoya University
4. Nagoya
5. Japan
6. Department of Chemistry
7. The Hong Kong University of Science and Technology
8. Kowloon
9. Hong Kong
Abstract
A di(o-tolyl)borylgold complex added to CO/N double bond to form Au–C and B–O/N bonds. DFT calculations revealed a two-step mechanism consisting of the coordination of O/N atom to B atom followed by nucleophilic migration of Au atom.
Funder
Ministry of Education, Culture, Sports, Science and Technology
Research Grants Council, University Grants Committee
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05478J
Reference128 articles.
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