Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex toward polar multiple bonds-Reference-Cited by-同舟云学术

Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex toward polar multiple bonds

Published:2021 Issue:3 Volume:12 Page:917-928
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Suzuki Akane¹²³⁴⁵,Guo Xueying⁶⁷⁸⁹^ORCID,Lin Zhenyang⁶⁷⁸⁹^ORCID,Yamashita Makoto¹²³⁴⁵^ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry

2. Graduate School of Engineering

3. Nagoya University

4. Nagoya

5. Japan

6. Department of Chemistry

7. The Hong Kong University of Science and Technology

8. Kowloon

9. Hong Kong

Abstract

A di(o-tolyl)borylgold complex added to CO/N double bond to form Au–C and B–O/N bonds. DFT calculations revealed a two-step mechanism consisting of the coordination of O/N atom to B atom followed by nucleophilic migration of Au atom.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05478J

Reference128 articles.

1. Transition Metal−Boryl Compounds: Synthesis, Reactivity, and Structure

2. Copper-catalyzed substitution of allylic carbonates with diboron: A new approach to allylboronate synthesis

3. Formal Nucleophilic Boryl Substitution of Organic Halides with Silylborane/Alkoxy Base System

4. Selective Synthesis of Organoboron Compounds with Copper(I)-Phosphine Complex Catalysts

5. Formal nucleophilic borylation and borylative cyclization of organic halides

Cited by 24 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Boryls, their compounds and reactivity: a structure and bonding perspective;Chemical Science;2024

2. Acyclic Boryl Complexes of Copper(I);Chemistry – A European Journal;2023-11-13

3. Reactions of Tetra(o‐tolyl)diborane(4) with Organic Azides: Formation of Fluorescent Boron‐Fused Hexazenes;Chemistry – A European Journal;2023-08-07

4. Synthesis of coordination compounds of dibutyltin(IV) with Schiff bases having nitrogen donor atoms;Journal of the Indian Chemical Society;2023-03

5. Cationic Symmetrically and Unsymmetrically Substituted Diboranes and Bis(diboranes) with Direct Boron‐Boron Bond: Synthesis by Substitution, Stability and Properties;European Journal of Organic Chemistry;2023-02-15