X-ray radiation-induced amorphization of metal–organic frameworks

Author:

Widmer Remo N.1234ORCID,Lampronti Giulio I.1234ORCID,Casati Nicola5678ORCID,Farsang Stefan1234ORCID,Bennett Thomas D.92104ORCID,Redfern Simon A. T.1234ORCID

Affiliation:

1. Department of Earth Sciences

2. University of Cambridge

3. Cambridge

4. UK

5. Paul Scherrer Institute

6. Photon Science Division

7. 5232 Villigen

8. Switzerland

9. Department of Materials Sciences & Metallurgy

10. Cambridge CB3 0FS

Abstract

Accumulation of radiation damage from synchrotron X-rays leads to complete amorphization of the initially crystalline metal–organic frameworks ZIF-4, ZIF-62, and ZIF-zni. The mechanism of this transformation is studied as a function of time and temperature and is shown to be non-isokinetic.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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