A ground-state-dominated magnetic field effect on the luminescence of stable organic radicals

Author:

Kimura Shun12345,Kimura Shojiro6784,Kato Ken91011124,Teki Yoshio91011124ORCID,Nishihara Hiroshi51013144,Kusamoto Tetsuro123415ORCID

Affiliation:

1. Department of Life and Coordination-Complex Molecular Science

2. Institute for Molecular Science

3. Okazaki

4. Japan

5. Department of Chemistry

6. Institute for Materials Research

7. Tohoku University

8. Sendai

9. Division of Molecular Materials Science

10. Graduate School of Science

11. Osaka City University

12. Osaka

13. The University of Tokyo

14. Tokyo

15. SOKENDAI (The Graduate University for Advanced Studies)

Abstract

We investigated the mechanism of the magnetic field effect (MFE) on the emission of a luminescent radical doped into host crystals. It was revealed that the spin sublevel population of radical dimers in the ground states is the key that governs the MFE.

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Iketani Science and Technology Foundation

Kato Foundation for Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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