Addressing the properties of “Metallo-DNA” with a Ag(i)-mediated supramolecular duplex
Author:
Affiliation:
1. Chemical Nanoscience Laboratory
2. School of Natural & Environmental Sciences
3. Newcastle University
4. Newcastle upon Tyne
5. UK
6. Chemistry
7. School of Engineering
Abstract
The silver-nucleoside complex [Ag(i)-(N3-cytidine)2]+, 1, self-assembles to form a supramolecular metal-mediated base-pair array highly analogous to those seen in metallo-DNA.
Funder
Newcastle University
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC05103H
Reference62 articles.
1. Structure of a Copper-Mediated Base Pair in DNA
2. Programmable self-assembly of metal ions inside artificial DNA duplexes
3. A Discrete Self-Assembled Metal Array in Artificial DNA
4. DNA-Metal Base Pairs
5. Metal-Mediated DNA Base Pairing: Alternatives to Hydrogen-Bonded Watson–Crick Base Pairs
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