Tunnelling in carbonic acid-Reference-Cited by-同舟云学术

Tunnelling in carbonic acid

Published:2016 Issue:50 Volume:52 Page:7858-7861
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wagner J. Philipp¹²³⁴⁵,Reisenauer Hans Peter¹²³⁴⁵^ORCID,Hirvonen Viivi¹²³⁴⁵,Wu Chia-Hua⁶⁷⁸⁹,Tyberg Joseph L.⁶⁷⁸⁹,Allen Wesley D.⁶⁷⁸⁹,Schreiner Peter R.¹²³⁴⁵

Affiliation:

1. Institute of Organic Chemistry

2. Justus-Liebig University

3. Heinrich-Buff-Ring 17

4. D-35392 Giessen

5. Germany

6. Center for Computational Quantum Chemistry and Department of Chemistry

7. University of Georgia

8. Athens

9. USA

Abstract

The cis,trans-conformer of carbonic acid (H₂CO₃), generated by near-infrared radiation, undergoes an unreported quantum mechanical tunnelling rotamerization with half-lives in cryogenic matrices of 4–20 h, depending on temperature and host material.

Funder

National Science Foundation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC01756H

Reference55 articles.

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2. Real-Time Observation of Carbonic Acid Formation in Aqueous Solution

3. H2CO3→ CO2+ H2O decomposition in the presence of H2O, HCOOH, CH3COOH, H2SO4and HO2radical: instability of the gas-phase H2CO3molecule in the troposphere and lower stratosphere

4. IMPLANTATION OF ENERGETIC D+IONS INTO CARBON DIOXIDE ICES AND IMPLICATIONS FOR OUR SOLAR SYSTEM: FORMATION OF D2O AND D2CO3

5. Spectroscopic detection of isolated carbonic acid

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