Ultrafast photogeneration of a metal–organic nitrene from 1,1′-diazidoferrocene-Reference-Cited by-同舟云学术

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Ultrafast photogeneration of a metal–organic nitrene from 1,1′-diazidoferrocene

Published:2024 Issue:18 Volume:15 Page:6707-6715
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Scherz‡ Frederik¹^ORCID,Bauer‡ Markus²^ORCID,Domenianni Luis I.²^ORCID,Hoyer Carolin³,Schmidt Jonas²^ORCID,Sarkar Biprajit⁴³^ORCID,Vöhringer Peter²^ORCID,Krewald Vera¹^ORCID

Affiliation:

1. Department of Chemistry, Theoretical Chemistry, TU Darmstadt, Peter-Grünberg-Str. 4, 64287 Darmstadt, Germany

2. Clausius-Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Wegelerstraße 12, 53115 Bonn, Germany

3. Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstraße 34-36, 14195, Berlin, Germany

4. Institute of Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

Abstract

A bent azide intermediate is key to form 1-azido-1′-nitrenoferrocene from 1,1′-diazidoferrocene, as shown with UV-pump–mid-IR-probe transient absorption spectroscopy and density functional theoryTD-DFT calculations including spin–orbit coupling.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00883A

Reference87 articles.

1. Ferrocene – 65 Years After

2. Ferrocene: Ironclad History or Rashomon Tale?

3. Cyclopentadien-Metallkomplexe, ein neuer Typ metallorganischer Verbindungen

4. A New Type of Organo-Iron Compound

5. 114. Dicyclopentadienyliron

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