Transient directing ligand- and solvent-controlled C–H/C–H cross-coupling/quaternization cyclization/dequaternization of benzaldehydes with thiophenes-Reference-Cited by-同舟云学术

Transient directing ligand- and solvent-controlled C–H/C–H cross-coupling/quaternization cyclization/dequaternization of benzaldehydes with thiophenes

Published:2019 Issue:52 Volume:55 Page:7518-7521
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sun Denan¹²³⁴⁵,Du Jiping¹²³⁴⁵,Fang Hao¹²³⁴⁵,Lan Jingbo¹²³⁴⁵^ORCID,Wu Di¹²³⁴⁵^ORCID,You Jingsong¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Green Chemistry and Technology of Ministry of Education

2. College of Chemistry

3. Sichuan University

4. Chengdu 610064

5. P. R. China

Abstract

Rh(iii)-Catalyzed C–H/C–H cross-coupling between benzaldehydes and thiophenes has been developed to construct ortho-heteroaryl benzaldehydes, phenanthridinium- and phenanthridine-type polycycles.

Funder

National Natural Science Foundation of China

Sichuan University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC04017J

Reference36 articles.

1. Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

2. Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

3. Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components

4. Pd-catalyzed ortho-arylation of phenylacetamides, benzamides, and anilides with simple arenes using sodium persulfate

5. Synthesis of Phenanthridinones from N-Methoxybenzamides and Arenes by Multiple Palladium-Catalyzed CH Activation Steps at Room Temperature

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