A one-pot strategy to synthesize β-ketophosphonates: silver/copper catalyzed direct oxyphosphorylation of alkynes with H-phosphonates and oxygen in the air-Reference-Cited by-同舟云学术

A one-pot strategy to synthesize β-ketophosphonates: silver/copper catalyzed direct oxyphosphorylation of alkynes with H-phosphonates and oxygen in the air

Published:2015 Issue:18 Volume:51 Page:3846-3849
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Xin¹²³⁴,Li Xu¹²³⁴,Chen Xiao-Lan¹²³⁴,Qu Ling-Bo¹²³⁴⁵,Chen Jian-Yu¹²³⁴,Sun Kai¹²³⁴,Liu Zhi-Dong¹²³⁴,Bi Wen-Zhu¹²³⁴,Xia Ying-Ya¹²³⁴,Wu Hai-Tao¹²³⁴,Zhao Yu-Fen¹²³⁴⁶

Affiliation:

1. College of Chemistry and Molecular Engineering

2. Zhengzhou University

3. Zhengzhou City

4. China

5. Chemistry and Chemical Engineering School

6. Department of Chemistry

Abstract

A highly efficient one-pot strategy has been developed for the synthesis of β-ketophosphonates directly from alkynes and dialkylH-phosphonates in the presence of widely available AgNO₃/CuSO₄and K₂S₂O₈at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C4CC10312B

Reference52 articles.

1. The Utility of Phosphonate Carbanions in Olefin Synthesis

2. Olefin synthesis with organic phosphonate carbanions

3. The Wittig olefination reaction and modifications involving phosphoryl-stabilized carbanions. Stereochemistry, mechanism, and selected synthetic aspects

4. S. E. Kelly , in Comprehensive Organic Synthesis, ed. B. M. Trost and I. Fleming, Pergamon, Oxford, 1991, vol. 1, pp. 729–818 and references therein

5. β-Ketophosphonates as β-lactamase inhibitors: Intramolecular cooperativity between the hydrophobic subsites of a class D β-lactamase

Cited by 101 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Photoinduced Transition‐Metal‐Free Chemodivergent Phosphorylation‐Peroxidation and Oxyphosphorylation of Alkenes;Advanced Synthesis & Catalysis;2024-08-22

2. Earth Abundant Transition Metal Catalysts: New and Efficient Tools for Hydrophosphination and Oxyphosphination of Alkenes and Alkynes;ChemCatChem;2024-07-16

3. HFIP‐Triggered Reduction Radical Coupling of Enamides with Alkynes Towards β‐Keto Alkylamides via H‐Bonding Electron Transfer;ChemCatChem;2024-07-16

4. 1,1-Oxycarbonation of Terminal Alkynes via Sequential Borylation, 1,2-Migration, and Oxidation with Oxone;Organic Letters;2024-03-29

5. Light/air-induced direct oxyphosphinylation of terminal alkynes with diarylphosphine oxides toward β-ketophosphine oxides;Tetrahedron Letters;2023-12